Predicting macroinvertebrate average score per taxon (ASPT) at water quality monitoring sites in Japanese rivers.

Biomonitoring with bioindicators such as river macroinvertebrates is fundamental for assessing the status of freshwater ecosystems. In Japan, water quality and biomonitoring surveys are conducted separately, leading to a lack of nationwide information on their relationships and the biological status of water quality monitoring (WQM) sites. To understand the biological status of WQM sites across Japan, we developed a multiple linear regression model to estimate the average score per taxon (ASPT) using river macroinvertebrate data surveyed at a total of 237 "aligned" sites based on the co-occurrence of biomonitoring and WQM sites. The resulting regression model with eight predictors, such as biological oxygen demand, the proportion of urban areas in the catchment, could predict ASPT with reasonable accuracy (e.g., an error of ±1 for 96% of the aligned data). Using this model, we estimated ASPT values at 2925 WQM sites in rivers nationwide, categorizing them into four levels of river environment quality: "very good" (29% of WQM sites), "good" (50%), "fairly good" (14%), and "not good" (8%). Furthermore, we observed statistically significant correlations (p < 0.05; 0.4 ≤ r ≤ 0.7) between ASPT and all eight macroinvertebrate metrics examined, such as mayfly and stonefly richness, providing ecological implications of changes in ASPT.

Residents' Willingness to Pay for Water Pollution Treatment and Its Influencing Factors: a Case Study of Taihu Lake Basin.

This study designs a double-bounded dichotomous questionnaire, and uses the Contingent Valuation Method (CVM) to estimate residents' willingness to pay(WTP) for water pollution control along the Taihu Lake Basin. The results of the returned questionnaire show that 82.76% of the residents are willing to pay. CVM estimation results show that the average WTP of residents for water pollution control is 138.86 yuan/year. In addition, the influencing factors of WTP are explored using a Logistic regression model, and the heterogeneity of WTP among residents of different genders is analyzed. The study found that: (1) The younger the residents, the higher their WTP; (2) The higher the income, the higher the residents' WTP for water pollution control; (3) Residents with higher educational level are more willing to pay; (4) The higher the degree of residents' understanding of water pollution control policies, the higher the WTP; (5) The higher the degree of residents' recognition of pro-environmental behavior, the higher the WTP; (6) Male residents' WTP is mainly affected by cognitive factors such as their understanding of governance policies and their approval of pro-environmental behaviors, while female residents' WTP is mainly affected by personal attributes, such as age, income, and the number of household laborers. Furthermore, this study proposes targeted measures to improve residents' WTP from three aspects: the government enriches the channels for residents to participate in water pollution control, the social media enriches the popularization of water environment knowledge, and the school strengthens the education of environmental protection knowledge, considering the differences in residents' characteristics. Therefore, this study can provide a theoretical reference and decision-making basis for encouraging residents to participate in water pollution control, promote the construction of a beautiful watershed, and provide a reference for other basins.

Water quality monitoring and modeling for an urban storm drainage channel in Thane, India.

The absence of a sewer system and inadequate wastewater treatment plants results in a discharge of untreated wastewater to the urban drainage channels and pollutes receiving waters. Field visits were carried out to observe water quality parameters such as dissolved oxygen (DO), biochemical oxygen demand (BOD), and chemical oxygen demand (COD) in an urban drainage system (Kolshet drain) in Thane City, Mumbai Metropolitan Region, India. Dye-tracing studies using rhodamine WT dye were used for computing the velocity, discharge, and dispersion coefficient of the drain. The data analysis shows that the BOD and COD values in the drain are higher than the permissible limits (30 mg L-1 for BOD and 250 mg L-1 for COD), which is not suitable for disposal to any receiving water body. Also, the DO was less than the permissible limit of a minimum of 3 mg L-1 (for the survival of aquatic life). It is seen that the higher BOD load significantly reduced the DO throughout the drain. The Water Quality Analysis Simulation Program (WASP 8.32, 2019) developed by the US Environmental Protection Agency (USEPA) has been used for the simulation of the DO and BOD in the drainage channel. The model simulates an appropriate estimate of the expected variation of DO and BOD at points of interest. The modeling for the Kolshet drain is expected to enable better estimates of the wastewater parameters and the pollution transport in the drain for planning purposes.

Bioconcentration potential of ionic liquids: New data on membrane partitioning and its comparison with predictions obtained by COSMOmic.

Ionic liquids (ILs) have recently gained significant attention in both the scientific community and industry, but there is a limited understanding of the potential risks they might pose to the environment and human health, including their potential to accumulate in organisms. While membrane and storage lipids have been considered as primary sorption phases driving bioaccumulation, in this study we used an in vitro tool known as solid-supported lipid membranes (SSLMs) to investigate the affinity of ILs to membrane lipid - phosphatidylcholine and compare the results with an existing in silico model. Our findings indicate that ILs may have a strong affinity for the lipids that form cell membranes, with the key factor being the length of the cation's side chain. For quaternary ammonium cations, increase in membrane affinity (logMA) was observed from 3.45 ± 0.06 at 10 carbon atoms in chain to 4.79 ± 0.06 at 14 carbon atoms. We also found that the anion can significantly affect the membrane partitioning of the cation, even though the anions themselves tend to have weaker interactions with phospholipids than the cations of ILs. For 1-methyl-3-octylimidazolium cation the presence of tricyanomethanide anion caused increase in logMA to 4.23 ± 0.06. Although some of our data proved to be consistent with predictions made by the COSMOmic model, there are also significant discrepancies. These results suggest that further research is needed to improve our understanding of the mechanisms and structure-activity relationships involved in ILs bioconcentration and to develop more accurate predictive models.

Heavy metal contamination and environmental risk assessment: a case study of surface water in the Bahr Mouse stream, East Nile Delta, Egypt.

Water, as an indispensable constituent of life, serves as the primary source of sustenance for all living things on Earth. The contamination of surface water with heavy metals poses a significant global health risk to humans, animals, and plants. Sharkiya Governorate, situated in the East Nile Delta region of Egypt, is particularly susceptible to surface water pollution due to various industrial, agricultural, and urban activities. The Bahr Mouse Stream, crucial for providing potable water and supporting irrigation activities in Sharkiya Governorate, caters to a population of approximately 7.7 million inhabitants. Unfortunately, this vital water source is exposed to many illegal encroachments that may cause pollution and deteriorate the water resource quality. In a comprehensive study conducted over two consecutive seasons (2019-2020), a total of 38 surface water samples were taken to assess the quantity of heavy metals in surface water destined for human consumption and other applications, supported by indices and statistics. The assessment utilized flame atomic absorption spectrophotometry to determine the concentration of key heavy metals including iron (Fe), manganese (Mn), cadmium (Cd), copper (Cu), lead (Pb), zinc (Zn), nickel (Ni), cobalt (Co), and chromium (Cr). The calculated mean value of the Water Quality Index (WQI) was found to be 39.1 during the winter season and 28.05 during the summer season. This value suggests that the surface water maintains good quality and is suitable for drinking purposes. Furthermore, the analysis indicated that the concentrations of heavy metals in the study area were below the recommended limits set by the World Health Organization and fell within the safe threshold prescribed by Egyptian legislation. Despite the identification of localized instances of illegal activities in certain areas, such as unauthorized discharges, the findings affirm that the Bahr Mouse stream is devoid of heavy metal pollution. This underscores the importance of continued vigilance and regulatory enforcement to preserve the integrity of these vital water resources.

Graphene aerogels as efficient adsorbers of water pollutants and their effect of drying methods.

Environmental accidents highlight the need for the development of efficient materials that can be employed to eliminate pollutants including crude oil and its derivatives, as well as toxic organic solvents. In recent years, a wide variety of advanced materials has been investigated to assist in the purification process of environmentally compromised regions, with the principal contestants being graphene-based structures. This study describes the synthesis of graphene aerogels with two methods and determines their efficiency as adsorbents of several water pollutants. The main difference between the two synthesis routes is the use of freeze-drying in the first case, and ambient pressure drying in the latter. Raman spectroscopy, Scanning Electron Microscopy (SEM), X-ray diffraction (XRD), X-ray Photoelectron Spectroscopy (XPS) and contact angle measurements are employed here for the characterisation of the samples. The as-prepared aerogels have been found to act as photocatalysts of aqueous dye solutions like methylene blue and Orange G, while they were also evaluated as adsorbents of organic solvents (acetone, ethanol and methanol), and, oils like pump oil, castor oil, silicone oil, as well. The results presented here show that the freeze-drying approach provides materials with better adsorption efficiency for the most of the examined pollutants, however, the energy and cost-saving advantages of ambient-pressure-drying could offset the adsorption advantages of the former case.

Geochemistry and origin of inorganic contaminants in soil, river sediment and surface water in a heavily urbanized river basin.

Understanding the geochemistry and contamination of rivers affected by anthropogenic activities is paramount to water resources management. The Asopos river basin in central Greece is facing environmental quality deterioration threats due to industrial, urban and agricultural activities. Here, the geochemistry of river sediments and adjacent soil in terms of major and trace elements (Al, Ca, Mg, Cd, Cr, Cu, Fe, Mn, Ni, Pb and Zn) and the geochemical composition of surface water in terms of major ions, trace elements and nutrients along the Asopos river basin were determined. In addition, this study characterized potential nitrate sources through the analysis of stable isotope composition of NO3- (δ15Ν-ΝΟ3- and δ18Ο-ΝΟ3-). Results indicated that specific chemical constituents including nutrients (NO2-, NH4+, PO43-) and major ions (Na+, Cl-) were highest in the urban, industrialized and downstream areas. On the other hand, nitrate (NO3-) concentration in river water (median 7.9 mg/L) showed a decreasing trend from the upstream agricultural sites to the urban area and even more in the downstream of the urban area sites. Ionic ratios (NO3-/Cl-) and δ15Ν-ΝΟ3- values (range from +10.2 ‰ to +15.7 ‰), complemented with a Bayesian isotope mixing model, clearly showed the influence of organic wastes from septic systems and industries operating in the urban area on river nitrate geochemistry. The interpretation of geochemical data of soil and river sediment samples demonstrated the strong influence of local geology on Cr, Fe, Mn and Ni content, with isolated samples showing elevated concentrations of Cd, Cu, Pb and Zn, mostly within the industrialized urban environment. The calculation of enrichment factors based on the national background concentrations provided limited insights into the origin of geogenic metals. Overall, this study highlighted the need for a more holistic approach to assess the impact of the geological background and anthropogenic activities on river waters and sediments.

Morphological variations and demographic responses of the Mediterranean pond turtle Mauremys leprosa to heterogeneous aquatic habitats.

Human activities affect terrestrial and aquatic habitats leading to changes at both individual and population levels in wild animal species. In this study, we investigated the phenotype and demographics of the Mediterranean pond turtle Mauremys leprosa (Schweigger, 1812) in contrasted environments of Southern France: two peri-urban rivers receiving effluents from wastewater treatment plants (WWTP), and another one without sewage treatment plant. Our findings revealed the presence of pesticides and pharmaceuticals in the three rivers of investigation, the highest diversities and concentrations of pollutants being found in the river subsections impacted by WWTP effluents. Principal component analysis and hierarchical clustering identified three levels of habitat quality, with different pollutant concentrations, thermal conditions, nutrient, and organic matter levels. The highest turtle densities, growth rates, and body sizes were estimated in the most disturbed habitats, suggesting potential adult benefits derived from harsh environmental conditions induced by pollution and eutrophication. Conversely, juveniles were the most abundant in the least polluted habitats, suggesting adverse effects of pollution on juvenile survival or adult reproduction. This study suggests that turtles living in polluted habitats may benefit from enhanced growth and body size, at the expense of reproductive success.

Polychlorinated biphenyl congeners in water canals and their relationships with water quality parameters: Insights into their risk assessment.

Water pollution with pesticides is one of the most important environmental problems. Polychlorinated biphenyls (PCBs) reach water bodies via agricultural discharge. The aim of this study was to determine the contamination of different water bodies with PCB congeners, and detect the correlation between water quality parameters and seasonal distribution of these PCBs. The results indicated that water canals of AlGharbiah showed the highest ranges of temperature, total dissolved solids (TDS) in spring, and dissolved oxygen (DO) in autumn, while AlQaliobiah water bodies witnessed the highest pH and electrical conductivity (EC) ranges in summer. The highest range of a PCB congener was that of PCB44 (7.96-118.29 µg/g) in sediment samples of Giza, followed by its range (18.01-85.44 µgL-1) in surface water of AlQaliobiah. We found a potential cancer risk from dermal contact with all the investigated PCBs. Principal component analysis (PCA) showed positive correlations between most PCBs and each of EC and TDS, and a negative correlation with DO. While the correlation between PCBs and each of temperature and pH varied according to the geographic location of the governorate. In conclusion, the investigated water canals were contaminated with PCBs, which posed a potential cancer risk and deteriorated water quality.

Suitability of treated wastewater for irrigation and its impact on groundwater resources in arid coastal regions: Insights for water resources sustainability.

Water scarcity threatens agriculture and food security in arid regions like Saudi Arabia. The nation produces significant quantities of municipal wastewater, which, with adequate treatment, could serve as an alternative water source for irrigation, thereby reducing reliance on fossil and non-renewable groundwater. This study assessed the appropriateness of using treated wastewater (TWW) for irrigation in a dry coastal agricultural region in Eastern Saudi Arabia and its impact on groundwater resources. Field investigations were conducted in Qatif to collect water samples and field measurements. A multi-criteria approach was applied to evaluate the TWW's suitability for irrigation, including complying with Saudi Standards, the Irrigation Water Quality Index (IWQI), the National Sanitation Foundation water quality index (NSFWQI), and the individual irrigation indices. In addition, the impact of TWW on groundwater was assessed through hydrogeological and isotope approaches. The results indicate that the use of TWW in the study area complied with the Saudi reuse guidelines except for nitrate, aluminum, and molybdenum. However, irrigation water quality indices classify TWW as having limitations that necessitate the use for salt-tolerant crops on permeable and well-drained soils. Stable isotopic analysis (δ2H, δ18O) revealed that long-term irrigation with TWW affected the shallow aquifer, while deep aquifers were minimally impacted due to the presence of aquitard layer. The application of TWW irrigation has successfully maintained groundwater sustainability in the study area, as evidenced by increased groundwater levels up to 2.3 m. Although TWW contributes to crop productivity, long term agricultural sustainability could be enhanced by improving effluent quality, regulating irrigation practices, implementing buffer zones, and monitoring shallow groundwater. An integrated approach that combines advanced wastewater treatment methods, community involvement, regulatory oversight, and targeted monitoring is recommended to be implemented.

Evaluation of potentially toxic elements and microplastics in the water treatment facility.

The potentially harmful effects of consuming potentially toxic elements (PTEs) and microplastics (MPs) regularly via drinking water are a significant cause for worry. This study investigated PTEs (Cd, Cu, Cr, Ni, Pd, Zn, Co), MPs, turbidity, pH, conductivity, and health risk assessment in the water treatment plant in Kielce, Poland. Zn had the highest concentrations throughout the water treatment facility, whereas Cd, Pb, and Co had lower concentrations (< 0.1 µg/L). The order of the concentrations among the specified PTEs was like Zn˃Cu˃Ni˃Cr˃Cd˃Pb and Co. The minimum turbidity was 0.34, and the maximum was 1.9 NTU. The range of pH in water samples was 6.51-7.47. The conductivity was 1,203-1,445 ms in water samples. These identified MPs were categorized into fiber and fragments. The color of these identified MPs was blue, red, black, green, and transparent. The minimum and maximum size of the MPs was 196 and 4,018 µm, while the average size was 2,751 ± 1,905 µm. The average concentration of MPs per liter of the water treatment plant was 108.88 ± 55.61. The elements listed are C, O, Na, Mg, Al, Si, K, Ca, and Ti. Fe and Zn were the predominant elements seen using EDX. HQ values of the PTEs were less than one for adults and children. The human health risk associated with all detected PTEs revealed that the HQ values exhibit a satisfactory degree of non-carcinogenic adverse health risk. HI values for adults and children age groups were less than one. In most water treatment samples, the carcinogenic value exceeds the threshold value of 10-6. The PTEs and MP concentrations in drinking water should be periodically monitored to minimize consumers' environmental pollution and health risks.

Synthesis of MnFe2O4/activated carbon derived from durian shell waste for removal of indole in water: Optimization, modelling, and mechanism.

While durian shell is often discharged into landfills, this waste can be a potential and zero-cost raw material to synthesize carbon-based adsorbents with purposes of saving costs and minimizing environmental contamination. Indole (IDO) is one of serious organic pollutants that influence aquatic species and human health; hence, the necessity for IDO removal is worth considering. Here, we synthesized a magnetic composite, denoted MFOAC, based on activated carbon (AC) derived from durian shell waste supported by MnFe2O4 (MFO) to adsorb IDO in water. MFOAC showed a microporous structure, along with a high surface area and pore volume, at 518.9 m2/g, and 0.106 cm3/g, respectively. Optimization of factors affecting the IDO removal of MFOAC were implemented by Box-Behnken design and response surface methodology. Adsorption kinetics and isotherms suggested a suitable model for MFOAC to remove IDO. MFOAC was recyclable with 3 cycles. Main interactions involving in the IDO adsorption mechanism onto MFOAC were clarified, including pore filling, n-π interaction, π-π interaction, Yoshida H-bonding, H-bonding.

Application of Artificial Neural Network (ANN) as a predictive tool for the removal of pharmaceutical from wastewater streams using biochar: a multifunctional technology for environment sustainability.

This study investigates biochar as an attractive option for removing pharmaceuticals from wastewater streams utilizing data from various literature sources and also explores the sensitivity of the characteristics and implementation of biochar. ANN 1 was designed to determine the optimal biochar characteristics (Surface Area, Pore Volume) to achieve the maximum percentage removal of pharmaceuticals in wastewater streams. ANN 2 was developed to identify the optimal biomass feedstock composition, pyrolysis conditions (temperature and time), and chemical activation (acid or base) to produce the optimal biochar from ANN 1. ANN 3 was developed to investigate the effectiveness of the biochar produced in ANN 1 and 2 in removing dye from water. Biomass feedstock with a high lignin content and high volatile matter at a high pyrolysis temperature, whether using an acid or base, achieves a high mesopore volume and high surface area. The biochar with the highest surface area and mesopore volume achieved the highest removal percentage. Regardless of hydrophobicity conditions, at low dosages (0.2), a high surface area and pore volume are required for a high percent removal. And with a higher dosage, a lower surface area and pore volume is necessary to achieve a high percent removal.

Determination of caffeine in treated wastewater discharged in the Nile River with emphasis on the effect of zinc and physicochemical factors.

The present study aimed to investigate the occurrence of caffeine residues in the Nile River according to drainage of treated wastewater at Assiut, Egypt, and the effects of physicochemical parameters and zinc on its concentration. Four different sites were selected to perform the study: S, wastewater treatment plant (WWTP) canal (source site); J, a junction site between WWTP canal and the Nile; R, a reference site in the Nile before J site; and A, a site located after J site in the Nile. Water and sediment samples were collected in Summer 2022 and Winter 2023. Caffeine and Zn concentrations and physicochemical parameters were measured in the collected samples. The caffeine concentrations in water samples ranged from 5.73 to 53.85 µg L-1 at S in winter and summer, respectively, while those in sediment ranged from 0.14 mg kg-1 at R in winter to 1.54 mg kg-1 at S in summer. Caffeine and Zn concentrations were higher in summer samples. The Water Quality Index (WQI) of the collected samples recorded the lowest values in winter season at S and J sites. The study found that caffeine and zinc concentrations are positively correlated with water temperature and conductivity, while negatively correlated with pH. The association between caffeine and Zn highlights the environmental impact of heavy metals and pharmaceutical residues, and stresses the need for future research on these interactions.

Carbon nanotubes buckypapers: A new frontier in wastewater treatment technology.

Occurrence of contaminants in water is one of the major global concerns humanity is still facing today: most of them are extremely toxic and dangerous for human health, obliging their removal for a proper and correct process of sanitation. Among wastewater treatment technologies, in the view of development of sustainable and environmentally friendly processes, membrane adsorption has proved to be a fast and simple method in the removal of pollutants, offering great contaminants recovery percentages, fast adsorbent regeneration and recycle, and easy scale-up. Due to their large surface area and tunable chemistry, carbon nanotubes (CNTs)-based materials revealed to be extraordinary adsorbents, exceeding by far performances of ordinary organic and inorganic membranes such as polyethersulfone, polyvinylidene fluoride, polytetrafluoroethylene, ceramics, currently employed in membrane technologies for wastewater treatment. In consideration of this, the review aims to summarize recent developments in the field of carbon nanotubes-based materials for pollutants recovery from water through adsorption processes. After a brief introduction concerning what adsorption phenomenon is and how it is performed and governed by using carbon nanotubes-based materials, the review discusses into detail the employment of three common typologies of CNTs-based materials (CNTs powders, CNTs-doped polymeric membranes and CNTs membranes) in adsorption process for the removal of water pollutants. Particularly focus will be devoted on the emergent category of self-standing CNTs membranes (buckypapers), made entirely of carbon nanotubes, exhibiting superior performances than CNTs and CNTs-doped polymeric membranes in terms of preparation strategy, recovery percentages of pollutants and regeneration possibilities. The extremely encouraging results presented in this review aim to support and pave the way to the introduction of alternative and more efficient pathways in wastewater treatment technologies to contrast the problem of water pollution.

Monitoring of university wastewater within the sewage system and its performance evaluation through integrated constructed wetlands.

Rapid increase in population and industrialization has not only improved the lifestyle but adversely affected the quality and availability of water leading to ample amount of wastewater generation. The major contribution towards wastewater production is from sewage. Regular monitoring and treatment of sewage water is necessary to conserve and enhance the quality of water. The present study focuses on monitoring of sewage water within the sewage system of a residential university. A total of 16 samples from different manholes were collected for physicochemical and heavy metals analysis and compared with final effluent collected from integrated constructed wetlands (ICWs) to assess its removal efficiency. The mean concentrations of influent and effluent were compared with national environmental quality standards (NEQS) for municipal discharge (pH 6-9, COD 150 mg/L, TSS 200 mg/L and TDS 3500 mg/L) and international agricultural reuse standards (IARS) (pH 6-8, COD <150 mg/L, TSS < 100 mg/L) respectively. Among all physicochemical parameters, influent values for chemical oxygen demand (COD) (169.56-258.36) mg/L exceeded the limit of NEQS for discharge into inland waters, whereas for total suspended solids (TSS) the concentration exceeded for discharge into STP (406 mg/L) and inland waters (202.33 mg/L). However, effluent concentrations for all the parameters were found within the permissible limit set by IARS. The removal efficiency for different parameters such as phosphate- phosphorus (PO43-P), COD, TSS, total dissolved solids (TDS) and total kjeldahl nitrogen (TKN) were 52, 53, 54, 35, and 36%, respectively. Heavy metal concentrations were compared with WHO guidelines among which lead (Pb) in effluent and chromium (Cr) in influent exceeded the limit (Pb 0.01 and Cr 0.05 mg/L). Interpolation results showed that zone 2 was highly contaminated in comparison to zone 1 & 3. Statistical analysis showed that correlation of physicochemical parameters and heavy metals was found significant (p < 0.05).

River water pollution in Lebanon: the country's most underestimated public health challenge.

Background: Due to the several interconnected crises that Lebanon has been facing for the past 4 years, many important social and environmental issues have been overlooked until more "pressing" ones are dealt with. Consequently, water pollution in Lebanon continues to worsen. Aim: This study aimed to describe the microbiological and chemical properties of the 10 main rivers in Lebanon and to assess their suitability for irrigation, while exploring some of the solutions to the problem. Methods: This cross-sectional study evaluated the pollution level of water from 10 rivers in Lebanon in June 2023 and their suitability for irrigation. Samples were collected at 3°C and their quality parameters were measured. Statistical analysis was conducted using R statistical software version 4.0.2. Results: Compared to the Food and Agriculture Organization (FAO) guidelines for safe irrigation water use, 4 out of the 10 samples had pH levels exceeding the permissible threshold, resulting in severe limitations on their usability. Three rivers had nitrate concentrations that exceeded the approved range, thus constraining their severe usage. Among the rivers, 60% had Escherichia coli levels higher than the permissible spectrum and 40% had faecal coliform counts exceeding FAO's upper limit recommendation. All water sources, however, had total dissolved solid levels that were within the recommended range. Conclusions: Polluted water can have a negative impact on human, wildlife and ecosystem health. Most of the assessed rivers in our study contained bacterial colonies, above the maximum recommended internationally. There is therefore an urgent need to address pollution issues in Lebanese waters to make them suitable for irrigation and other uses.

Effect of marine ecological compensation policy on coastal water pollution: Evidence from China based on a multiple period difference-in-differences approach.

With the development and utilization of marine resources, coastal water pollution has become increasingly prominent. The marine ecological compensation (MEC) is a key measure to balance the utilization of marine resources and the protection of marine environment. This paper attempts to explore the governance effect of MEC policy on coastal water pollution. Based on panel data of coastal cities in China from 2006 to 2020, a multiple period difference-in-differences (DID) model is used to estimate the impact of MEC policy on coastal water pollution. The research results show that the coastal water pollution has decreased significantly in the polit cities after implementing the MEC policy. The governance effect of MEC policy on coastal water pollution will last for three year and cover areas within a geographical distance of 200 km. The transmission mechanisms of MEC policy on coastal water pollution are the reduction of land-based sewage, marine technological progress and optimization of industrial structure. Further, this paper provides operational suggestions for strengthening the governance effect of MEC policy on coastal water pollution.

Regional evaluation of glyphosate pollution in the minor irrigation network.

Due to its low cost, its ease of use and to the "mild action" declared for long time by the Control and Approval Agencies towards it, the herbicide Glyphosate, is one of the currently best-selling and most-used agricultural products worldwide. In this work, we evaluated the presence and spread of Glyphosate in the Po River Basin (Northern Italy), one of the regions with the most intensified agriculture in Europe and where, by now for decades, a strong and general loss of aquatic biodiversity is observed. In order to carry out a more precise study of the real presence of this herbicide in the waters, samples were collected from the minor water network for two consecutive years, starting in 2022, at an interval time coinciding with those of the spring and summer crop treatments. In contrast to the sampling strategies generally adopted by Environmental Protection Agencies, a more focused sampling strategy was adopted to highlight the possible high concentrations in minor watercourses in direct contact with cultivated fields. Finally, we investigated the possible consequences that the higher amounts of Glyphosate found in our monitoring activities can have on stress reactions in plant (Groenlandia densa) and animal (Daphnia magna) In all the monitoring campaigns we detected exceeding European Environmental Quality Standard - EQS limits (0.1 µg/L) values. Furthermore, in some intensively agricultural areas, concentrations reached hundreds of µg/L, with the highest peaks during spring. In G. densa and D. magna, the exposition to increasing doses of herbicide showed a clear response linked to metabolic stress. Overall, our results highlight how, after several decades of its use, the Glyphosate use efficiency is still too low, leading to economic losses for the farm and to strong impacts on ecosystem health. Current EU policy indications call for an agroecological approach necessary to find alternatives to chemical weed control, which farms can develop in different contexts in order to achieve the sustainability goals set by the Farm to Fork strategy.

Remarkable purification of organic dyes by NiOOH-modified industrial waste residues.

Extracting functional materials from industrial waste residues to absorb organic dyes can maximize waste reuse and minimize water pollution. However, the extraordinarily low purification efficiency still limits the practical application of this strategy. Herein, the lamellar NiOOH is in-situ anchored on the industrial waste red mud surface (ARM/NiOOH) as an adsorbent to purify organic dyes in wastewater. ARM/NiOOH adsorbent with high specific surface area and porosity provides considerable active sites for the congo red (CR), thereby significantly enhancing the removal efficiency of CR. Besides, we fit a reasonable adsorption model for ARM/NiOOH adsorbent and investigate its adsorption kinetics. Resultantly, ARM/NiOOH adsorbent can remarkably adsorb 348.0 mg g-1 CR within 5 min, which is 7.91 times that of raw RM. Our work provides a strategy for reusing industrial waste and purifying sewage pollution, which advances wastewater treatment engineering.